Superman Man of Steel #22 (1993)
1st full appearance of Steel (John Henry Irons)
Superman Man of Steel (1991–2003) back issues at Republic Comics: 2 in stock. Real photos of every copy, graded by hand, shipped from Canada.
1st full appearance of Steel (John Henry Irons)
1st Superman black costume
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Series dates from the Grand Comics Database, CC BY-SA 4.0.